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Coming together to design the next Moodle.

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Co-author Baris Key, a research chemist at Argonne, conducted nuclear magnetic resonance (NMR) spectroscopy experiments. These tests were among the first steps to experimentally prove that magnesium ions could move through the material as rapidly as the theoretical studies had predicted.

“It was crucial to confirm the fast magnesium hopping experimentally. It is not often that the theory and the experiment agree closely with each other,” Key said. “The solid state NMR experiments for this chemistry were very challenging and would not be possible without dedicated resources and a funding source such as JCESR. As we’ve shown in this study, an in-depth understanding of short- and long-range structure and ion dynamics will be the key for magnesium ion battery research.”

NMR is akin to magnetic resonance imaging (MRI), which is routinely used in medical settings, where it shows hydrogen atoms of water in human muscles, nerves, fatty tissue, and other biological substances. But researchers can also tune NMR frequency to detect other elements, including the lithium or magnesium ions that are found in battery materials.

The NMR data from the magnesium scandium selenide material, however, involved material of unknown structure with complex properties, making them challenging to interpret.

Canepa noted the challenges of testing materials that are so new. “Protocols are basically non-existent,” he said. “These findings were only possible by combining a multi-technique approach (solid-state NMR and synchrotron measurements at Argonne) in addition to conventional electrochemical characterization.”

The team plans to do further work to use the conductor in a battery. “This probably has a long way to go before you can make a battery out of it, but it’s the first demonstration you can make solid-state materials with really good magnesium mobility through it,” Ceder said. “Magnesium is thought to move slowly in most solids, so nobody thought this would be possible.”

Additionally, the research identified two related fundamental phenomena that could significantly affect the development of magnesium solid electrolytes in the near future, namely, nike air max 1 black sail mensajes
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Bo, now an assistant professor at Shanghai Jiao Tong University, said the discovery could have a dramatic effect on the energy landscape. “This work brought together a great team of scientists from various scientific disciplines, and took the first stab at the formidable challenge of building a solid-state magnesium battery,” he said. “Although currently in its infancy, this emerging technology may have a transformative impact on energy storage in the near future.”

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